1380096-92-3Relevant academic research and scientific papers
Sulfinyl-Mediated Stereoselective Overman Rearrangements and Diels-Alder Cycloadditions
Colomer, Ignacio,Gheewala, Chirag,Simal, Carmen,Velado, Marina,Fernández De La Pradilla, Roberto,Viso, Alma
, p. 4081 - 4087 (2016)
Sulfinyl trichloroacetamides are readily obtained in excellent yields through a highly stereoselective Overman rearrangement. Related bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with total chemo- and diastereoselectivity. These amido dienyl sulfoxides undergo highly selective Diels-Alder cycloadditions with N-phenylmaleimide with remarkable stereocontrol by the sulfoxide moiety.
