1380097-01-7

Upstream product

• 1380096-51-4 (+)-(4S,2E,5E,S(S))-5-(p-tolylsulfinyl)deca-2,5-dien-4-ol 
• 545-06-2 trichloroacetonitrile 
• 1380096-72-9 C₁₉H₂₄Cl₃NO₂S 

Relevant academic research and scientific papers

Sulfinyl-Mediated Stereoselective Overman Rearrangements and Diels-Alder Cycloadditions

Sulfinyl trichloroacetamides are readily obtained in excellent yields through a highly stereoselective Overman rearrangement. Related bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with total chemo- and diastereoselectivity. These amido dienyl sulfoxides undergo highly selective Diels-Alder cycloadditions with N-phenylmaleimide with remarkable stereocontrol by the sulfoxide moiety.

Sulfinyl-mediated stereoselective overman rearrangements and Diels-Alder cycloadditions

The Overman rearrangement of allylic sulfinyl trichloroacetimidates affords sulfinyl trichloroacetamides with high stereoselectivity and excellent yields. Bis-allylic substrates lead to amido 2-sulfinyl butadiene derivatives in excellent yields, with tota