138021-87-1Relevant articles and documents
Synthesis of (-)-alantrypinone
Hart, David J.,Magomedov, Nabi
, p. 5429 - 5432 (1999)
A synthesis of (-)-alantrypinone is described. The synthesis features the use of [Me3AlSPh]Li as a promoter of a 4-iminobenzoxazine to 4- quinazolinone rearrangement and as a reagent for the deprotection of an Fmoc- protected amino acid derivat
Synthesis of ent-alantrypinone
Hart,Magomedov
, p. 5892 - 5899 (2007/10/03)
This paper presents a synthesis of ent-alantrypinone (ent-6), the enantiomer of a natural product produced by the fungus Penicillium thymicola. The synthesis revolves around the Li[Me3AlSPh]-promoted isomerization of iminobenzoxazine 33 to quin