1380210-72-9

Upstream product

• 1380210-51-4 C₁₉H₃₀ClNO₃Si 
• 1380210-59-2 (4S,5S)-4-[(tert-butyldimethylsilyloxy)methyl]-5-[(E)-3-chloroprop-1-enyl]-2-phenyl-4,5-dihydrooxazole 
• 933468-31-6 N-benzoyl-O-((tert-butyl)-dimethylsilyl)-(S)-serine methyl ester 
• 933468-32-7 C₁₈H₃₀N₂O₄Si 
• 1380210-47-8 (S,E)-N-[1-(tert-butyldimethylsilyloxy)-6-chloro-3-oxohex-4-en-2-yl]benzamide 
• 1380210-55-8 C₁₉H₃₀ClNO₃Si 
• 18162-48-6 tert-butyldimethylsilyl chloride 

Downstream Products

• 1380210-89-8 (4S,5R,6S)-4-(hydroxymethyl)-2-phenyl-6-(tetradec-1-enyl)-5,6-dihydro-4H-1,3-oxazin-5-ol 
• 1380210-80-9 (4S,5R,6S)-5-(tert-butyldimethylsilyloxy)-4-[(tert-butyldimethylsilyloxy)methyl]-2-phenyl-6-(tetradec-1-enyl)-5,6-dihydro-4H-1,3-oxazine 

Relevant academic research and scientific papers

Total syntheses of D -xylo- and D -arabino-phytosphingosine based on the syntheses of chiral 1,3-oxazines

An efficient, stereocontrolled, and short synthetic method for the preparation D-xylo- and D-arabino-phytosphingsine was achieved utilizing chiral oxazines. The key features of this strategy are the stereoselective intramolecular oxazine formation catalyzed by palladium(0) and an intermolecular olefin cross-metathesis reaction.