138023-29-7Relevant academic research and scientific papers
HETEROADAMANTANES AND THEIR DERIVATIVES. XXII. SYNTHESIS OF 3,6-DIAZAHOMOADAMANTANE-9-SPIROOXIRANES
Kuznetsov, A. I.,Serova, T. M.,Nghi, Tran,Vladimirova, I. A.,Moskovkin, A. S.
, p. 391 - 395 (2007/10/02)
3,6-Diazahomoadamantane-9-spirooxiranes were obtained by the reaction of 3,6-diazahomoadamantan-9-ones with dimethylsulfoxoniomethanide. It was found that the oxirane ring is opened highly regioselectively by nucleophilic reagents.
HETEROADAMANTANES AND THEIR DERIVATIVES. 14. SYNTHESIS OF 3,6-DIAZAHOMOADAMANTAN-3-OLS AND THEIR ACETATES
Kuznetsov, A. I.,Vladimirova, I. A.,Serova, T. M.,Moskovkin, A. S.
, p. 631 - 635 (2007/10/02)
The reduction of 3,6-diazahomoadamantan-9-ones with metal hydrides gave 3,6-diazahomoadamantan-9-ols, which were converted to acetates by the action of acetic anhydride.The effect of the substituents in the nodal positions on the rates of reduction and ac
