1380232-63-2Relevant articles and documents
Nickel catalyzed dealkoxylative Csp2-Csp3 cross coupling reactions - Stereospecific synthesis of allylsilanes from enol ethers
Guo, Lin,Leiendecker, Matthias,Hsiao, Chien-Chi,Baumann, Christoph,Rueping, Magnus
, p. 1937 - 1940 (2015)
The application of cyclic and acyclic enol ethers as electrophiles in cross coupling reactions offers new possibilities for the preparation of functional compounds. A novel nickel catalyzed dealkoxylative cross coupling reaction allows access to structurally diverse allylsilanes and alcohol derivatives with high stereospecificity and in good yields under mild reaction conditions directly from the corresponding enol ethers.
Copper-catalyzed trifluoromethylation of allylsilanes
Shimizu, Ryo,Egami, Hiromichi,Hamashima, Yoshitaka,Sodeoka, Mikiko
supporting information; experimental part, p. 4577 - 4580 (2012/06/18)
CF3 on Csp3: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The reaction of allylsilanes without a substituent in the 2-position gave vinylsilane derivative
