1380233-00-0Relevant articles and documents
Trifluoromethylation of allylsilanes under copper catalysis
Mizuta, Satoshi,Galicia-Lopez, Oscar,Engle, Keary M.,Verhoog, Stefan,Wheelhouse, Katherine,Rassias, Gerasimos,Gouverneur, Veronique
, p. 8583 - 8587 (2012)
Branched allylic CF3 products are accessible by copper-catalyzed trifluoromethylation of allylsilanes with the Togni reagent I. The silyl group is critical to control the outcome of this reaction because in its absence, a product of addition be
Copper-catalyzed trifluoromethylation of allylsilanes
Shimizu, Ryo,Egami, Hiromichi,Hamashima, Yoshitaka,Sodeoka, Mikiko
supporting information; experimental part, p. 4577 - 4580 (2012/06/18)
CF3 on Csp3: Trifluoromethylation of allylsilane derivatives was accomplished through the use of CuI and Togni's reagent (1) under mild conditions. The reaction of allylsilanes without a substituent in the 2-position gave vinylsilane derivative