138024-37-0Relevant academic research and scientific papers
A New Synthesis of Hindered Unsymmetrical t-Alkyl Ethers
Masada, Hiromitsu,Gotoh, Hidenori,Ohkubo, Makoto
, p. 1739 - 1742 (1991)
The unusual Williamson reactions of t-butyl and t-pentyl halides with lithium t-alkoxides or with t-alkyl alcohols and amines were carried out at 20-50 deg C.Some of the nucleophilic substitution products were new unsymmetrical ethers: t-butyl t-pentyl ether, t-butyl 1,1-dimethyl-2-propenyl ether, t-butyl 1,1-dimethyl-2-propynyl ether, 1,1-dimethyl-2-propynyl t-pentyl ether, and t-butyl 1-ethyl-1-methyl-2-propynyl ether.
