1380240-10-7Relevant articles and documents
Copper-Catalyzed Cross-Coupling of Vinyliodonium Salts and Zinc-Based Silicon Nucleophiles
Zhang, Liangliang,Oestreich, Martin
, p. 8061 - 8063 (2018)
A silylation of vinyliodonium salts using zinc-based silicon reagents as nucleophiles is reported. This cross-coupling is catalyzed by copper, and vinylsilanes are obtained in high yield likely following a Cu(I)/Cu(III) reaction mechanism. The procedure i
Enantioselective α-vinylation of aldehydes via the synergistic combination of copper and amine catalysis
Skucas, Eduardas,MacMillan, David W. C.
supporting information; experimental part, p. 9090 - 9093 (2012/07/14)
The enantioselective α-vinylation of aldehydes using vinyl iodonium triflate salts has been accomplished via the synergistic combination of copper and chiral amine catalysis. These mild catalytic conditions provide a direct route for the enantioselective construction of enolizable α-formyl vinylic stereocenters without racemization or olefin transposition. These high-value coupling adducts are readily converted into a variety of useful olefin synthons.