1380244-56-3Relevant academic research and scientific papers
Stereoselective Total Synthesis of the Non-Contiguous Polyketide Natural Product (–)-Dolabriferol
Gantasala, Naresh,Borra, Suresh,Pabbaraja, Srihari
, p. 1230 - 1240 (2018)
The stereoselective total synthesis of the non-contiguous polypropionate dolabriferol has been accomplished in 17 steps, by an approach that is both divergent and convergent. The key reactions involved are enantioselective cross-aldol coupling, aldol dime
In silico inspired total synthesis of (-)-dolabriferol
Currie, Russell H.,Goodman, Jonathan M.
, p. 4695 - 4697 (2012/06/18)
Going retro: The diazabicycloundecane-induced retro-Claisen rearrangement of a linear precursor serves as the key step to form the hindered ester of the polypropionate dolabriferol (1, see scheme, PMB=p-methoxybenzyl, PMP=p-methoxyphenyl, TES=triethylsilyl). The rearrangement is thought to mimic the biosynthetic formation of 1. Copyright
