1380396-89-3

Basic information

• Product Name: ethyl (2E)-5-acetyl-4-(4-fluorophenyl)-2-methyl-6-oxohept-2-enoate
• CAS NO: 1380396-89-3
• Molecular Weight: 320.361
• Mol File: 1380396-89-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl (2E)-5-acetyl-4-(4-fluorophenyl)-2-methyl-6-oxohept-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl (2E)-5-acetyl-4-(4-fluorophenyl)-2-methyl-6-oxohept-2-enoate(1380396-89-3)
• EPA Substance Registry System: ethyl (2E)-5-acetyl-4-(4-fluorophenyl)-2-methyl-6-oxohept-2-enoate(1380396-89-3)

Safety Data

• Hazardous Substances Data: 1380396-89-3(Hazardous Substances Data)

Upstream product

• 123-54-6 acetylacetone 
• 189626-04-8 4-(4-fluorophenyl)-2-methylbuta-2,3-dienoic acid ethyl ester 

Relevant articles and documents

Controlled reactions of 2,3-allenoates with a 1,3-diketone catalyst effect

Two types of reactions of 2,3-allenoates with 1,3-diketones under different reaction conditions are described: under palladium catalysis, the relatively electron-rich C=C bonds are attacked to afford ethyl (2E)-4-acyl-2-alkyl-4-aryl- 6-oxohept-2-enoates exclusively with dicyclohexyl(2,4,6-trimethoxyphenyl) phosphane as the ligand; under Cu(OAc)2 catalysis, 4-[R-C(=O)-]-(LB-Phos) 3,5-dialkyl-3-(2-oxo-2-arylethyl)furan-2(3H)-one products are formed unexpectedly through intramolecular reaction at the electron-deficient C=C bond.