1380425-97-7Relevant academic research and scientific papers
Rhodium-catalyzed allylic substitution reactions with indium(III) organometallics
Riveiros, Ricardo,Tato, Ruben,Perez Sestelo, Jose,Sarandeses, Luis A.
experimental part, p. 3018 - 3023 (2012/07/03)
A novel rhodium-catalyzed allylic substitution reaction using indium organometallics is reported. Aryl- and heteroarylindium reagents reacted in THF at 80 °C with primary and secondary allyl halides and their derivatives under rhodium(I) catalysis to afford the α-substituted products in good yields and with high regio- and stereoselectivity. The reaction takes place with substoichiometric amounts of the triorganoindium reagents, which demonstrates the efficiency of the indium-rhodium transmetallation process in carbon-carbon bond-forming reactions. Copyright
