1380499-75-1Relevant academic research and scientific papers
Synthesis and characterization of N,N-chelate manganese complexes and applications in C[sbnd]N coupling reactions
Das, Kuhali,Kumar, Amol,Jana, Akash,Maji, Biplab
supporting information, (2019/12/28)
Bidentate NN-ligands have been derived from the reaction between aldehydes and 2-(aminomethyl)pyridine. The treatment of these ligands with Mn(CO)5Br gave complexes that are highly bench stable. The complexes were characterized by various analytical and spectral methods. Single-crystal XRD of complex Mn-2 was performed, which indicates an octahedral geometry around the metal center. The complexes efficiently catalyze the N-alkylation of anilines with alcohols under optimized reaction conditions.
Acid-promoted rearrangement of arylmethyl azides: Applications toward the synthesis of N-arylmethyl arenes and polycyclic heteroaromatic compounds
Tummatorn, Jumreang,Thongsornkleeb, Charnsak,Ruchirawat, Somsak
experimental part, p. 4732 - 4739 (2012/07/28)
An acid-promoted Aubé-Schmidt's rearrangement of arylmethyl azides provides a useful in situ iminium ion intermediate, which can be efficiently trapped by various nucleophiles. We report here the reaction of this iminium ion with aromatic nucleophiles to
