1380588-83-9

Upstream product

• 4526-07-2 1,4-bis(trimethylsilyl)-1,3-butadiyne 
• 4526-06-1 trimethylsilyl-1,3-butadiyne 
• 368455-15-6 diethyl 5-iodo-1,3-benzenedicarboxylate 

Downstream Products

• 1380588-84-0 1,3-diethoxycarbonyl-5-(butadiynyl)benzene 
• 1380588-85-1 C₅₄H₄₂O₁₂ 
• 1397275-11-4 1,3,5-tris[(1,3-diethylcarboxylate-5-(4-(ethynyl)phenyl))butadiynyl]-benzene 
• 1397275-09-0 1,3-diethylcarboxylate-5-[(4-(trimethylsilylethynyl)phenyl)butadiynyl]-benzene 
• 1397275-10-3 1,3-diethylcarboxylate-5-[(4-(ethynyl)phenyl)butadiynyl]-benzene 

Relevant academic research and scientific papers

METAL-ORGANIC FRAMEWORK MATERIALS WITH ULTRAHIGH SURFACE AREAS

A metal organic framework (MOF) material including a Brunauer-Emmett-Teller (BET) surface area greater than 7,010 m2/g. Also a metal organic framework (MOF) material including hexa-carboxylated linkers including alkyne bond. Also a metal organic framework (MOF) material including three types of cuboctahedron cages fused to provide continuous channels. Also a method of making a metal organic framework (MOF) material including saponifying hexaester precursors having alkyne bonds to form a plurality of hexa-carboxylated linkers including alkyne bonds and performing a solvothermal reaction with the plurality of hexa-carboxylated linkers and one or more metal containing compounds to form the MOF material.

Metal-organic framework materials with ultrahigh surface areas: Is the sky the limit?

We have synthesized, characterized, and computationally simulated/validated the behavior of two new metal-organic framework (MOF) materials displaying the highest experimental Brunauer-Emmett-Teller (BET) surface areas of any porous materials reported to

Designing higher surface area metal-organic frameworks: Are triple bonds better than phenyls?

We have synthesized, characterized, and computationally validated the high Brunauer-Emmett-Teller surface area and hydrogen uptake of a new, noncatenating metal-organic framework (MOF) material, NU-111. Our results imply that replacing the phenyl spacers of organic linkers with triple-bond spacers is an effective strategy for boosting molecule-accessible gravimetric surface areas of MOFs and related high-porosity materials.