1380596-96-2Relevant academic research and scientific papers
A new entry of highly nucleophilic CHBr3-TiCl4-Mg system for the stereoselective synthesis of 1-alkenyl bromides
Bhorge, Yeshwant Ramchandra,Chang, Su-Haur,Chang, Cheng-Ta,Yan, Tu-Hsin
, p. 4846 - 4851 (2012)
This TiCl4-Mg promoted coupling of CHBr3 with various aldehydes and ketones, especially in sterically hindered or enolizable ketones, provides a simple, practical, and stereoselective carbonyl-bromomethylenation leading primarily to (E)-vinyl bromides.
