1380681-06-0Relevant academic research and scientific papers
Meerwein's reagent mediated, significantly enhanced nucleophilic fluorination on alkoxysilanes
Jorapur, Yogesh R.,Shimada, Toyoshi
supporting information; experimental part, p. 1064 - 1068 (2012/06/17)
We developed a new facile method to fluorosilanes from alkoxysilanes using Meerwein's reagent. Our protocol afforded fluorosilanes in excellent yields in various organic solvents including acetonitrile under mild reaction conditions at room temperature. We also proposed a reaction mechanism with the probable silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.
An efficient method for the synthesis of symmetrical disiloxanes from alkoxysilanes using Meerwein's reagent
Jorapur, Yogesh R.,Shimada, Toyoshi
supporting information; experimental part, p. 1633 - 1638 (2012/08/07)
We report here a new and efficient route to symmetrical disiloxanes from their corresponding alkoxysilanes using Meerwein's reagent as mediator and potassium carbonate as additive under mild reaction conditions in acetonitrile. Our methodology is very simple, economic, and high yielding. We have also proposed a reaction mechanism with the plausible silyloxonium intermediates. Georg Thieme Verlag Stuttgart · New York.
