1380708-60-0

Basic information

• Product Name: (Z)-butyl 3-(3-bromophenyl)-2-methylbut-2-enoate
• CAS NO: 1380708-60-0
• Molecular Weight: 311.219
• Mol File: 1380708-60-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-butyl 3-(3-bromophenyl)-2-methylbut-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-butyl 3-(3-bromophenyl)-2-methylbut-2-enoate(1380708-60-0)
• EPA Substance Registry System: (Z)-butyl 3-(3-bromophenyl)-2-methylbut-2-enoate(1380708-60-0)

Safety Data

• Hazardous Substances Data: 1380708-60-0(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 7785-64-0 (E)-butyl 2-methylbut-2-enoate 
• 80-59-1 Tiglic acid 

Relevant articles and documents

Undirected arene and chelate-assisted olefin C-H bond activation: [Rh IIICp*]-catalyzed dehydrogenative alkene-arene coupling as a new pathway for the selective synthesis of highly substituted Z olefins

Undirected/Directed Cross-Coupling: A new dehydrogenative Rh III-catalyzed cross-coupling reaction between bromoarenes bearing no directing group and vinylic substrates substituted by a chelating group is reported. An original reaction mechanism enables the use of internal alkenes in a Z-selective coupling. The application of 1,3-disubstituted or 1,2-homodisubstituted arenes leads to the formation of highly functionalized, complex, and valuable olefins as one single isomer. Copyright