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[2 + 4] Cycloadditions between germenes and α-ethylenic aldehydes and ketones: A route to germaoxacyclohexenes
Lazraq,Escudié,Couret,Satgé,Soufiaoui
, p. 555 - 558 (2008/10/08)
Dimesityl(fluorenylidene)germene (1) reacts with various α-ethylenic aldehydes and ketones to afford, by a [2 + 4] cycloaddition, the six-membered-ring heterocycles 2-7. Hydrolysis of these germaoxacyclohexenes leads to germylated aldehydes and ketones.
