1381768-88-2Relevant academic research and scientific papers
Palladium-catalyzed conjugate addition of terminal alkynes to enones
Villarino, Lara,Garcia-Fandino, Rebeca,Lopez, Fernando,Mascarenas, Jose L.
supporting information; experimental part, p. 2996 - 2999 (2012/08/28)
A practical protocol for the hydroalkynylation of enones using Pd catalysis is reported. The reaction proceeds efficiently with a variety of alkynes as well as with several cyclic and acyclic enones, providing synthetically relevant β-alkynyl ketones in good to excellent yields.
Rhodium-catalyzed asymmetric conjugate alkynylation of enones with alkynylsilanols
Nishimura, Takahiro,Tokuji, Sumito,Sawano, Takahiro,Hayashi, Tamio
experimental part, p. 3222 - 3225 (2009/12/05)
Asymmetric conjugate alkynylation of α,β-unsaturated ketones with (triisopropylsilyl)ethynylsilanols giving β-alkyny I ketones took place in high yields with high enantioselectivity in the presence of chiral rhodium catalysts.
