1381777-99-6

Basic information

• Product Name: xantphos copper chloride
• CAS NO: 1381777-99-6
• Molecular Weight: 677.629
• Mol File: 1381777-99-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: xantphos copper chloride(CAS DataBase Reference)
• NIST Chemistry Reference: xantphos copper chloride(1381777-99-6)
• EPA Substance Registry System: xantphos copper chloride(1381777-99-6)

Safety Data

• Hazardous Substances Data: 1381777-99-6(Hazardous Substances Data)

Upstream product

• 161265-03-8 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene 

Relevant articles and documents

Copper-Catalyzed Anti-Markovnikov Hydrosilylation of Terminal Alkynes

A copper-catalyzed anti-Markovnikov hydrosilylation of alkynes with PhSiH3 was reported. This reaction represents a notable and efficient example on copper-catalyzed hydrosilylatioin of alkynes, which shows excellent recognition between the terminal and internal triple bonds. Various (hetero)aromatic and aliphatic substituted terminal alkynes underwent this reaction to afford the (E)-vinylsilanes in high yields and with excellent regioselectivity.

Asymmetric total synthesis of (-)-amphidinolide v through effective combinations of catalytic transformations

An asymmetric total synthesis of (-)-amphidinolide V was accomplished. The synthesis features a base-catalyzed alkynyl silane alcoholysis/ring-closing enyne metathesis sequence for facile construction of a 1,3-diene motif. A diene RCM followed by a ring-c