1381800-47-0

Basic information

• Product Name: 5-(diethylamino)-2-{[(4-iodophenyl)imino]methyl}phenol
• Synonyms: 5-(diethylamino)-2-{[(4-iodophenyl)imino]methyl}phenol;5-(diethylamino)-2-{(E)-[(4-iodophenyl)imino]methyl}phenol
• CAS NO: 1381800-47-0
• Molecular Formula: C₁₇H₁₉IN₂O
• Molecular Weight: 394.25003
• Mol File: 1381800-47-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5-(diethylamino)-2-{[(4-iodophenyl)imino]methyl}phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 5-(diethylamino)-2-{[(4-iodophenyl)imino]methyl}phenol(1381800-47-0)
• EPA Substance Registry System: 5-(diethylamino)-2-{[(4-iodophenyl)imino]methyl}phenol(1381800-47-0)

Safety Data

• Hazardous Substances Data: 1381800-47-0(Hazardous Substances Data)

Upstream product

• 17754-90-4 4-(Diethylamino)salicylaldehyde 
• 540-37-4 p-aminoiodobenzene 

Relevant articles and documents

Single stranded helical chains of C-H?π interactions further connected by halogen-halogen interactions of type i to construct supramolecular structure of (E)-5-(diethylamino)-2-[(4-iodophenylimino)methyl]phenol compound

In this study, (E)-5-(diethylamino)-2-[(4-iodophenylimino)methyl]phenol compound was investigated from the point of stacking interactions assembling the supramolecular network, conformational isomerism and tautomerism. For this purpose, X-ray diffraction, FT-IR and UV/Vis spectroscopic techniques were used, giving the following structural and spectroscopic properties of the compound: The title compound has two conformers (anti and eclipsed) in the crystal structure resulting from rotation about C-N single bond of ethyl group. Both conformers prefer enol form in the solid state, adopting E configuration about the CN double bond. The supramolecular architecture of the compound is constructed by two non-covalent interactions as C-H?π and halogen-halogen interactions. The repetition of C-H?π interactions is resulted in a single-stranded helical structure. The helical structures are further connected by C-I?I-C interactions of Type I to construct the two dimensional supramolecular network defined as (6,3)-net in Wells nomenclature. The title compound adopts both enol and keto forms in EtOH (a polar and protic solvent) while enol form is preferred in the solid state.