13822-50-9

Usage

Synthesis application

Used for the synthesis of coordination compounds and catalysts in organometallic chemistry.

Complex formation

Can coordinate with transition metals to form stable complexes.

Utilization

Often utilized in the development of homogeneous catalysts for various organic transformations.

Reaction types

Involved in hydrogenation, hydroformylation, and coupling reactions.

Versatile nature

Its ability to influence the reactivity of metal centers makes it a valuable tool in chemical research and industrial applications.

Upstream product

• 16605-03-1 (3-aminopropyl)diphenylphosphine 
• 603-35-0 triphenylphosphine 
• 4376-01-6 sodium diphenylphosphide 

Downstream Products

• 49789-24-4 N-(3-Phenylphosphanyl-propyl)-benzamide 
• 68286-91-9 3-phenyl-[1,3]azaphosphinane-2-thione 
• 21200-06-6 3-phenyl-[1,3]azaphosphinane 
• 49789-40-4 (3-Aminopropyl)-butyl-phenylphosphin 
• 49789-23-3 N-(3-Phenylphosphanyl-propyl)-butyramide 
• 49789-21-1 N-(3-Phenylphosphanyl-propyl)-formamide 
• 49789-37-9 (3-Ureidopropyl)-phenylphosphin 
• 21286-98-6 <3-Amino-propyl>-phenyl-dithiophosphinsaeure-betain 
• 33730-82-4 2-phenyl-[1,2]azaphospholidine 
• 49789-28-8 (3-Phenylphosphanyl-propyl)-carbamic acid ethyl ester 
• 21200-09-9 5-phenyl-1-aza-5-phospha-spiro[5.5]undecane 
• 21200-08-8 2,3-diphenyl-[1,3]azaphosphinane 
• 49789-39-1 1-Phenyl-3-(3-phenylphosphanyl-propyl)-thiourea 
• 21200-07-7 2-ethyl-3-phenyl-[1,3]azaphosphinane 

Relevant academic research and scientific papers

Preparation and Characterization of Cobalt(III) Complexes Containing 4,7-Diphenyl-4,7-diphosphadecane-1,10-diamine and 4,8-Diphenyl-4,8-diphosphaundecane-1,11-diamine, NH2(CH2)3P(C6H5)(CH2)nP(C6H5)(CH2)3NH2 (n=2,3)

Twelve new cobalt(III) complexes of the types, cisα-p+ (L=2,4-pentanedionate (acac) and oxalate (ox) ions) (four complexes) and cisβ-p+ (eight complexes) were prepared and characterized by 1H NMR and absorption spectra, where rac(P)- and meso(P)-323NPPN denote rac(P)- and meso(P)-NH2(CH2)mP(C6H5)(CH2)nP(C6H5)(CH2)mNH2 with m=3 and n=2, and 333NPPN the ligand with m=3 and n=3.Reactivities of the complexes towards hydrochloric acid were examined and compared with those of the corresponding 222NPPN (m=2, n=2) and 232NPPN (m=2, n=3) complexes.All the cisα isomers yield the cisα-dichloro complexes, the 333NPPN and 222NPPN complexes being more reactive than the 232NPPN and 323NPPN complexes in which five- and six-membered chelate rings of NPPN are involved.For the cisβ isomers, the acac complexes afford +)>2+ except the rac(P)- and meso(P)-333NPPN complexes which give the trans-dichloro complexes, while all the ox complexes liberate the ox ion to yield the dichloro complex of the cisα, cisβ, or trans configuration.For both cisβ-acac and -ox isomers, the 222NPPN and 232NPPN complexes are more reactive than those of 323NPPN and 333NPPN, and the meso(P)-complexes are more reactive than the rac(P)-complexes.