138235-50-4Relevant academic research and scientific papers
Silacupration of Oxabicyclic Compounds. An Interrupted Ring Opening Reaction
Lautens, Mark,Belter, Randolph K.,Lough, Alan J.
, p. 422 - 424 (2007/10/02)
Oxabicyclooctenes have been found to undergo silacupration when treated with (PhMe2Si)Cu*LiCN.Ring closure of the cuprate onto a remote carbonyl group at C-3 provides tricyclic compounds.Trapping experiments with a variety of other electrophiles prior to the closure reaction have also been achieved.
