1383451-63-5Relevant academic research and scientific papers
Synthesis of aryl allyl alkynes via reaction with allyl amine and aryl alkynoic acids through decarboxylation
Lee, Jieun,Nam, Kye Chun,Lee, Sunwoo
, p. 1008 - 1015 (2020)
Allyl alkynoic esters were synthesized by the reaction of allyl amines and alkynoic acids via deaminative esterification. The reaction of allyl alkynoic esters with Pd(dba)2 and Xantphos in digylme at 110 °C for 12 h afforded the desired decarb
Multidirectional cobalt-catalyzed diels-alder/1,4-hydrovinylation sequences
Erver, Florian,Kuttner, Julian R.,Hilt, Gerhard
, p. 8375 - 8385 (2012/11/07)
The combination of two powerful cobalt-catalyzed carbon-carbon bond forming transformations, namely, the Diels-Alder and the 1,4-hydrovinylation reaction, in a tandem or a sequential one-pot procedure, opened up a concise and efficient route to polysubstituted aromatic systems and cyclohex-3-enone derivatives. Furthermore, ozonolysis of the latter products led to polycarbonyl compounds with tailored carbonyl group distances which could be characterized via their respective BF2-borinane complexes. The cobalt catalysts tolerated several functional groups, and a flexible approach to polyfunctionalized compounds in concise fashion was described.
