1383537-07-2Relevant academic research and scientific papers
Regio- and stereoselective syntheses of piperidine derivatives via ruthenium-catalyzed coupling of propargylic amides and allylic alcohols
Murugesan, Sathiyamoorthy,Jiang, Fan,Achard, Mathieu,Bruneau, Christian,Derien, Sylvie
supporting information; experimental part, p. 6589 - 6591 (2012/08/14)
Intermolecular selective coupling of linear allylic alcohols and propargylic amides occurs in the presence of a catalytic amount of the cationic ruthenium complex [Cp*Ru(NCCH3)3]PF6 followed by condensation to generate six-membered cyclic enamides or hemiaminal ethers with water as the only side product.
