1383543-47-2Relevant articles and documents
1-Bromo-2-(cyclopropylidenemethyl)benzene: A useful building block in the palladium-catalyzed reaction of 2-alkynylbenzenamine
Li, Shaoyu,Luo, Yong,Wang, Xiaocong,Guo, Minjie,Wu, Jie
, p. 1691 - 1696 (2012)
A novel palladium-catalyzed domino reaction of 1-bromo-2- (cyclopropylidenemethyl)benzene and 2-alkynylbenzenamine is reported, which generates 2-(naphthalen-2-yl)benzenamines and 5H-indeno[1,2-c]quinolines via 6-endo and 5-exo cyclization, respectively. The regioselectivity for the final outcome can be affected by phosphine and N-heterocyclic carbene ligands. Copyright