1383658-33-0Relevant articles and documents
Reaction of oxocyclobutenyl palladium(II) complex with terminal alkynes or organozincs affording differently 2,3-disubstituted cyclobutenones
Azami, Hidekazu,Miyashita, Masaki,Aoki, Daichi,Andou, Hidemi,Matsumura, Atsuki,Iwasaki, Masakazu
, p. 1285 - 1287 (2017)
The reaction of the oxocyclobutenyl palladium(II) complex 2 with terminal alkyne 3 in the presence of CuI or with organozincs yielded differently 2,3-disubstituted cyclobutenones 4 or 5 via the stoichiometric Sonogashira- or Negishi-type reactions, respec
Convenient Access to 2,3-Disubstituted-cyclobut-2-en-1-ones under Suzuki Conditions and Their Synthetic Utility
Alcaide, Benito,Almendros, Pedro,Lázaro-Milla, Carlos
, p. 7547 - 7552 (2019)
A regioselective synthesis of general applicability has been designed for the one-pot preparation of 2,3-disubstituted-cyclobutenones from iodoalkynes through cyclobutenylation, Suzuki CC coupling, and ketone formation. This one-pot methodology has been a
Efficient approach to 1,2-diazepines via formal diazomethylene insertion into the C-C bond of cyclobutenones
Sugimoto, Kenji,Hayashi, Rie,Nemoto, Hideo,Toyooka, Naoki,Matsuya, Yuji
, p. 3510 - 3513 (2012/07/31)
Efficient monocyclic 1,2-diazepine formation via a tandem electrocyclization reaction of cyclobutenones with lithiodiazoacetate is demonstrated. The reaction proceeds through an oxy anion-accelerated 4π-ring opening of cyclobutene followed by an 8π-ring closure of the resultant oxy anion-substituted diazo-diene under mild conditions to furnish a 1,2-diazepine via formal diazomethylene insertion into the C-C bond of cyclobutenone.