138382-77-1Relevant academic research and scientific papers
Anomeric effect on acidity: Experimental and theoretical studies on proton abstraction at anomeric center of 1,5-anhydro-4,6-O-benzylidene-2,3-dideoxy-3-C-nitro-D-hex-2-enitol
Sakakibara,Nishitani,Seta,Nakagawa
, p. 5809 - 5812 (1991)
The quasi-equatorial hydrogen atom at the anomeric center of the title compound was experimentally proved to be slightly more acidic than the quasi-axial one; this is supported by AM1 calculation.
