1383843-85-3Relevant academic research and scientific papers
Catalytic asymmetric synthesis of chiral phenols in ethanol with recyclable rhodium catalyst
Yao, Jian,Liu, Na,Yin, Long,Xing, Junhao,Lu, Tao,Dou, Xiaowei
supporting information, p. 4946 - 4950 (2019/09/30)
A general method to access diverse chiral phenols by rhodium-catalyzed asymmetric conjugate arylation using hydroxylated arylboronic acids in ethanol was developed. Recycling of the rhodium catalyst by flash chromatography on silica gel was feasible in this system. The synthetic utility of the strategy was demonstrated by efficient synthesis of chiral drug tolterodine.
Rh/chiral sulfinylphosphine catalyzed asymmetric 1,4-addition of arylboronic acids to chalcones
Chen, Guihua,Xing, Junwei,Cao, Peng,Liao, Jian
supporting information; experimental part, p. 5908 - 5911 (2012/09/07)
A general method to obtain enantioenriched 1,3,3-triarylpropan-1-ones bearing a diarylmethine stereocenter was developed using Rh/chiral sulfinylphosphine catalyzed 1,4-addition of arylboronic acids to chalcones. The catalysis progressed smoothly in the p
