1383845-35-9Relevant academic research and scientific papers
Synthesis of bis(4-methylphenylsulfonimidoyl)methane - The first free' geminal bis(sulfoximine)
Reggelin, Michael,Mehler, Christian,Kaiser, Janphilipp
, p. 1095 - 1098 (2012/06/04)
The synthesis of the first free' geminal bis(sulfoximine) bis(4-methylphenylsulfonimidoyl)methane is described. Herein we present two different synthetic routes leading either to the racemate or the enantiomerically pure compound. This representative of a new substance class can be regarded as a chiral analogue of the bis(iminophosphorane)s which are used as ligands in rare-earth-metal-catalyzed hydroamination reactions. Georg Thieme Verlag Stuttgart · New York.
