1383850-99-4

Upstream product

• 625-92-3 3,5-dibromopyridine 
• 1383850-97-2 3,5-bis(2,6-dimethylphenyl)pyridine 
• 1383851-11-3 C₂₇H₂₄N₃O₄⁽¹⁺⁾*Cl^(1-) 
• 2923-28-6 silver trifluoromethanesulfonate 
• 100379-00-8 2,6-dimethylbenzene boronic acid 

Downstream Products

• 1383851-04-4 3,5-bis(2,6-dimethylphenyl)-1-mesitylpyridine-2-thione 
• 1383851-07-7 4-(tert-butyl)-3,5-bis(2,6-dimethylphenyl)-1-mesityl-1,4-dihydropyridine 
• 1383851-08-8 3,5-bis(2',6'-dimethylphenyl)-1-mesityl-1,2-dihydropyridine 
• 1383851-09-9 3,5-bis(2,6-dimethylphenyl)-1-mesityl-1,4-dihydropyridine 
• 1383851-10-2 7,9-bis(2,6-dimethylphenyl)-2,4-dimethylpyrido[1,2-a]indole 
• 1383851-01-1 3,5-bis(2',6'-dimethylphenyl)-1-mesitylpyridin-1-ium trifluoromethanesulfonate 

Relevant academic research and scientific papers

1,3,5-Triaryl 2-pyridylidene: Base-promoted generation and complexation

We herein report a base-promoted generation of sterically hindered 1,3,5-triaryl 2-pyridylidene from the corresponding pyridinium salt. The thus-generated 2-pyridylidene was trapped by S8 and Me 2SAuCl to form 2-pyridinethione and a 2-pyridylidene-gold(i) complex, respectively. Rearrangement of pyridylidene to pyrido[1,2-a]indole indicates high reactivity of the carbene center of 2-pyridylidene.