1384063-06-2

Upstream product

• 1384062-97-8 (2R,3R)-methyl 2-hydroxy-3,7-dimethyl-3-((E)-prop-1-en-1-yl)-2-((E)-styryl)oct-6-enoate 
• 141-27-5 3,7-dimethyl-2,6-octadienal 
• 106-24-1 Geraniol 
• 34562-09-9 (S,E)-4,8-dimethylnona-3,7-dien-2-ol 
• 853065-81-3 1-methylgeraniol 

Relevant academic research and scientific papers

Highly stereoselective C-C bond formation by rhodium-catalyzed tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor carbenoids and chiral allylic alcohols

The tandem ylide formation/[2,3]-sigmatropic rearrangement between donor/acceptor rhodium carbenoids and chiral allyl alcohols is a convergent C-C bond forming process, which generates two vicinal stereogenic centers. Any of the four possible stereoisomers can be selectively synthesized by appropriate combination of the chiral catalyst Rh2(DOSP)4 and the chiral alcohol.