138423-69-5

Upstream product

• 115160-05-9 1-bromo-2,4,6-tris[bis(trimethylsilyl)methyl]benzene 
• 135139-78-5 (mesityl)(2,4,6-tris{bis(trimethylsilyl)methyl}phenyl)dihydrogermane 
• 2633-66-1 2-mesitylmagnesium bromide 
• 162088-69-9 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)bromochloro(mesityl)germane 
• 138423-68-4 GeS₄(C(C₆H₅)2)(C₆H₂(CH(Si(CH₃)3)2)3)(C₆H₂(CH₃)3) 
• 135139-69-4 5-[2,4,6-tris[bis(trimethylsilyl)methyl]phenyl]-5-mesityl-1,2,3,4,5-tetrathiagermolane 
• 908093-98-1 diazodiphenylmethane 

Downstream Products

• 138444-29-8 GeS₃(C(C₆H₅)2)(C₆H₂(CH(Si(CH₃)3)2)3)(C₆H₂(CH₃)3) 
• 162088-82-6 (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)hydroxy(mesityl)(methylthio)germane 
• 135139-74-1 [2,4,6-tris[bis(trimethylsilyl)methyl]phenyl](hyroxy)(mercapto)(mesityl)germane 
• 138423-68-4 GeS₄(C(C₆H₅)2)(C₆H₂(CH(Si(CH₃)3)2)3)(C₆H₂(CH₃)3) 

Relevant academic research and scientific papers

Synthesis and structure of novel germanium-containing cyclic polysulfides

Novel germanium-containing cyclic polysulfides 1,2,3,4,5-tetrathiagermolanes 5 (Tbt(Ar)-GeS4; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl; Ar = mesityl, 2,6-diethylphenyl, 2,4,6-triisopropylphenyl) have been synthesized, and the molecular structure of Tbt(Mes)GeS4 was determined by X-ray crystallographic analysis. Reaction of the tetrathiagermolanes 5 with diphenyldiazomethane gave 1,2,3,5-tetrathia-4-germacyclohexanes 10, 1,2,4,5-tetrathia-3-germacyclohexanes 11, and 1,2,4-trithia-3-germacyclopentanes 12. The structure of 1,2,3,5-tetrathia-4-germacyclohexane 10a was determined by X-ray structural analysis.

SYNTHESIS OF SMALL-RING SULFUR COMPOUNDS CONTAINING GERMANIUM AND TIN

Synthesis of some novel types of four-membered organosulfur compounds containing germanium and tin by cycloaddition of germanethione (R1R2Ge=S) and stannanethione (R1R2Sn=S) intermediates is reported.