1384282-27-2Relevant articles and documents
Evaluation of the chiral DIANANE backbone as ligand for organolithium reagents
Praz, Jezabel,Guenee, Laure,Aziz, Sarwar,Berkessel, Albrecht,Alexakis, Alexandre
experimental part, p. 1780 - 1790 (2012/07/28)
Novel endo,endo-2,5-diaminonorbonane-derived tertiary C2- symmetrical diamines were synthesized via the one-pot reductive amination of enantiomerically pure norbornane-2,5-dione. These ligands were applied to various catalytic reactions such as asymmetric deprotonation, asymmetric bromine-lithium exchange, and enantioselective addition of aryl- and allkylithium reagents to aromatic aldimines. Copyright