1384313-38-5Relevant articles and documents
Outer-sphere direction in iridium C-H borylation
Roosen, Philipp C.,Kallepalli, Venkata A.,Chattopadhyay, Buddhadeb,Singleton, Daniel A.,Maleczka, Robert E.,Smith, Milton R.
supporting information; experimental part, p. 11350 - 11353 (2012/08/29)
The NHBoc group affords ortho selective C-H borylations in arenes and alkenes. Experimental and computational studies support an outer sphere mechanism where the N-H proton hydrogen bonds to a boryl ligand oxygen. The regioselectivities are unique and com