1384432-67-0

Basic information

• Product Name: (E)-(4-bromo-2-methylbut-1-en-3-yn-1-yl)benzene
• Synonyms: (E)-(4-bromo-2-methylbut-1-en-3-yn-1-yl)benzene
• CAS NO: 1384432-67-0
• Molecular Weight: 221.096
• Mol File: 1384432-67-0.mol

Chemical Properties

• CAS DataBase Reference: (E)-(4-bromo-2-methylbut-1-en-3-yn-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(4-bromo-2-methylbut-1-en-3-yn-1-yl)benzene(1384432-67-0)
• EPA Substance Registry System: (E)-(4-bromo-2-methylbut-1-en-3-yn-1-yl)benzene(1384432-67-0)

Safety Data

• Hazardous Substances Data: 1384432-67-0(Hazardous Substances Data)

Upstream product

• 77295-77-3 (E)-(4,4-dibromo-2-methylbuta-1,3-dien-1-yl)benzene 
• 80907-80-8 (E)-(4,4-dibromo-2-methylbut-1,3-dien-1-yl)benzene 

Downstream Products

• 1384432-47-6 (E)-2-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)-1,2-thiazinane 1,1-dioxide 
• 1384432-37-4 (E)-N,3-dimethyl-N-(methylsulfonyl)-2-oxo-4-phenylbut-3-enamide 
• 1384432-38-5 (E)-N,3-dimethyl-N-(methylsulfonyl)-2-oxo-4-phenylbut-3-enamide 
• 1384432-26-1 N-cyclopropyl-N-(4-methyl-5-phenylfuran-2-yl)methanesulfonamide 
• 1384432-28-3 2-(4-methyl-5-phenylfuran-2-yl)-1,2-thiazinane 1,1-dioxide 
• 1384432-62-5 N-(3-iodo-4-methyl-5-phenylfuran-2-yl)-N-methylmethanesulfonamide 
• 1384432-45-4 (E)-N-cyclopropyl-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)methanesulfonamide 
• 1384432-41-0 (E)-N-methyl-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)methanesulfonamide 
• 1384432-46-5 (E)-4-methyl-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)-N-(methylsulfonyl)benzenesulfonamide 
• 1384432-27-2 N,4-dimethyl-N-(4-methyl-5-phenylfuran-2-yl)benzenesulfonamide 
• 1384432-44-3 (E)-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)-N-phenylmethanesulfonamide 
• 1384432-42-1 (E)-N-butyl-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)methanesulfonamide 
• 1384432-23-8 N-butyl-N-(4-methyl-5-phenylfuran-2-yl)methanesulfonamide 
• 1384432-43-2 (E)-N-benzyl-N-(3-methyl-4-phenylbut-3-en-1-yn-1-yl)methanesulfonamide 

Relevant articles and documents

Gold-Catalyzed Intermolecular Ynamide Amination-Initiated Aza-Nazarov Cyclization: Access to Functionalized 2-Aminopyrroles

A novel gold-catalyzed intermolecular ynamide amination-initiated aza-Nazarov cyclization has been developed, allowing the facile and efficient synthesis of various 2-aminopyrroles in moderate to good yields. Furthermore, a mechanistic rationale for this

Zinc-Catalyzed Stereo- and Regioselective 1,4-Hydrative Fluorination of 3-En-1-ynamides with Selectfluor

Zinc-catalyzed 1,4-oxofluorinations of 3-en-1-ynamides with Selectfluor in acetonitrile/water proceeded with high regio- and stereoselectivity, giving E-configured γ-fluoro-α,β-unsaturated amides efficiently. Our control experiments indicate that kinetica

Cu(I)-catalyzed oxidative cyclization of enynamides: Regioselective access to cyclopentadiene frameworks and 2-aminofurans

An efficient Cu(I)-catalyzed oxidative cyclization of alkynyl-tethered enynamides for the construction of fused bicyclic cyclopentadiene derivatives is disclosed. The cascade proceeds through alkyne oxidation, carbene/alkyne metathesis, and formal (3 + 2)

Gold-catalyzed synthesis of substituted 2-aminofurans via formal [4+1]-cycloadditions on 3-en-1-ynamides

Gold-catalyzed formal [4+1]-cycloadditions between 3-en-1-ynamides 1 and 8-methylquinoline oxide are reported. The success of this reaction relies on a hypothetic oxa-Nazarov cyclization on gold-stabilized allylic cations. Preliminary results on a new 1,2-difunctionalization of 3-en-1-ynamide are also reported.