1384872-76-7Relevant academic research and scientific papers
Synthesis and investigation of the metal-metal interactions in early/late heterobimetallic complexes linking group 5 imido fragments to Co(i)
Evers, Deirdra A.,Bluestein, Alia H.,Foxman, Bruce M.,Thomas, Christine M.
, p. 8111 - 8115 (2012)
Phosphinoamide ligands have been utilized to link a CoI center to a Nb or Ta imido fragment. The resulting heterobimetallic complexes, ICo(Ph2PNiPr)3MNtBu, have weakened dative metal-metal interactions as a result of the strongly donating imido ligand. These complexes can be reduced by 2 electrons to generate dinitrogen-bound complexes.
