138495-01-9Relevant academic research and scientific papers
Electroreductive acylation of aromatic imines with acylimidazoles
Kise, Naoki,Morimoto, Shinji
, p. 1765 - 1771 (2008/09/18)
The intermolecular reductive coupling of aromatic imines with acylimidazoles was effected by electroreduction in the presence of chlorotrimethylsilane and gave α-amino-α-aryl ketones. This method was also effective for the synthesis of α-amino-α-aryl esters using methoxycarbonylimidazole as an electrophile.
Electroreductive Coupling of Aromatic Imines with Electrophiles in the Presence of Chlorotrimethylsilane
Shono, Tatsuya,Kise, Naoki,Kunimi, Nobutaka,Nomura, Ryoji
, p. 2191 - 2194 (2007/10/02)
Electroreduction of aromatic imines in the presence of electrophiles gave the corresponding inter- and intramolecular coupling products when the reaction was carried out with the use of chlorotrimethylsilane (CTMS) as the trapping agent of an anion interm
