138535-18-9

Upstream product

• 68944-30-9 2-(3,5-di-tert-butylphenyl)-2-methylpropanenitrile 
• 157643-34-0 2-(3,5-di-t-butylphenyl)-2-methylpropanoic acid 
• 89738-84-1 (2,4,6-tri-tert-butylphenyl)magnesium bromide 

Downstream Products

• 157643-36-2 2-(3,5-di-t-butylphenyl)-2-methylpropylphosphonous dichloride 
• 157643-32-8 2-(3,5-di-t-butylphenyl)-2-methylpropylphosphine 
• 131066-15-4 5,5'-(2,5-dimethylhexane-2,5-diyl)bis(1,3-di-tert-butylbenzene) 
• 1460-02-2 1,3,5-Tri-tert-butylbenzene 
• 157643-35-1 1-(1-bromo-2-methylpropan-2-yl)-3,5-di-tert-butylbenzene 

Relevant academic research and scientific papers

Photolysis of (2,4,6-Tri-t-butylphenyl)bis(trimethylsilyl)phosphine

The photolysis of (2,4,6-tri-t-butylphenyl)bis(trimethylsilyl)phosphine in benzene gave products suggesting homolytic P-C bond cleavage followed by rearrangement and coupling.

Abnormal Reactions of Sterically Bulky Organometallics ArM (Ar = 2,4,6-Tri-t-butylphenyl, M = Li or MgBr) with Lead Dichloride

Reaction of ArLi (Ar: 2,4,6-tri-t-butylphenyl), generated from ArBr and n-BuLi, or ArMgBr with lead dichloride resulted in the formation of plumbane Ar'3PbBr, diplumbane (Ar'3Pb)2, and Ar'OH having a rearranged group Ar' (Ar': 2-(3,5-di-t-butylphenyl)-2-m