138537-73-2Relevant academic research and scientific papers
Synthesis of unsymmetrical dinucleating ligands bearing nitrogen and oxygen donor atoms
Fenton, David E.,Papageorgiou, George
, p. 5913 - 5928 (2007/10/03)
The synthesis of unsymmetrical dinucleating ligands bearing nitrogen and oxygen donor atoms is described. The Schiff-base condensation of functionalised salicylaldehyde derivatives with primary amines gave rise to unsymmetrical unsaturated ligands, whereas condensation with secondary amines followed by in situ reduction of the iminium species with sodium borohydride, led to the formation of unsymmetrical saturated ligands. The latter were also prepared by the tandem Mannich reactions of 4-chlororesorcinol.
Unsymmetric Dicopper(II) Complexes of Dinucleating Ligands bearing Chemically Distinct Co-ordination Environments
Crane, Jonathan D.,Fenton, David E.,Latour, Jean Marc,Smith, Arnold J.
, p. 2979 - 2988 (2007/10/02)
Dicopper(II) complexes of unsymmetrical dinucleating Schiff-base ligands bearing chemically distinct co-ordination sites have been prepared and their properties studied.The ligands were derived from the condensation of 4-bromo-2-formyl-6-(4-methylpiperazi
