13858-09-8Relevant articles and documents
Hocking, W. H.,Williams, M. L.,Gerry, M. C. L.
, p. 250 - 260 (1975)
Photochemistry of ClNCO
Gilbert, J. V.,Coombe, R. D.
, p. 4082 - 4085 (1988)
The gas phase chemistry that occurs after the photolysis of ClNCO at 248 nm is characterized by the action of two excited intermediates, N(2D) and N2(A).Each of these reacts with ClNCO to generate NCO(A 2Σ+), and blue emission from the NCO(A 2Σ+ -> X 2Π) transition is observed.The time profile of the NCO emission consists of two distinct components, a fast component arising from the N(2D) + ClNCO reaction and a slow component arising from the N2(A) + ClNCO reaction.The N(2D) is an initial photofragment and the N2(A ) is generated in the N(2D) + ClNCO reaction.The value of the rate constant for N(2D) + ClNCO is determined to be 7.0 +/- 0.8 * 10-11 cm3 s-1.The rate constant measured from the decay of the NCO emission in a previous work (2.1 +/- 0.2 * 10-11 cm3 s-1 ) is assigned to the N2(A) + ClNCO reaction.
Isolierung und Photoisomerisierung von einfach substituierten Nitriloxiden
Maier, Guenther,Teles, Joaquim Henrique
, p. 152 - 153 (2007/10/02)
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