138604-24-7

Upstream product

• 29783-26-4 cis-4-cyclopentene-1,3-diol 
• 4083-64-1 Tosyl isocyanate 
• 158361-26-3 N,N′-ditosyl-meso-cyclopent-4-ene-1,3-diol biscarbamate 

Downstream Products

• 441768-86-1 (R)-4-(tert-butyldimethylsilanyloxy)-4-[(S)-1-(toluene-4-sulfonyl)-2,5-dihydro-1H-pyrrol-2-yl]butan-1-ol 
• 441768-85-0 N-allyl-N-((1S,5R)-5-hydroxycyclopent-2-enyl)-4-methylbenzenesulfonamide 
• 320718-06-7 N-allyl-N-((1S,5R)-5-[tert-butyldimethylsilanyloxy)cyclopent-2-enyl]-4-methylbenzenesulfonamide 
• 320718-10-3 (S)-2-[(R)-1-(tert-butyldimethylsilanyloxy)but-3-enyl]-1-(toluene-4-sulfonyl)-2,5-dihydro-1H-pyrrole 
• 72741-87-8 swainsonine 
• 143668-59-1 N-((1S,5R)-5-hydroxycyclopent-2-enyl)-4-methylbenzenesulfonamide 

Relevant academic research and scientific papers

Palladium catalyzed asymmetric reactions assisted by P*,P*-bidentate bisdiamidophosphites based on 1,4-diols

A small series of P*,P*-bidentate bisdiamidophosphite ligands containing 1,3,2-diazaphospholidine rings have been prepared. The cationic [Pd(allyl)(P*,P*)]BF4and neutral [Pd(P*,P*)Cl2] palladium(II) complexes were synthesized with on

Diamidophosphite–oxazolines with a pyridine core in Pd-catalyzed asymmetric reactions

We have designed and synthesized a small library of readily available P,N,N-diamidophosphite–oxazoline ligands containing 1,3,2-diazaphospholidine rings and a pyridine moiety. The use of these ligands provides up to 96% ee in Pd-catalyzed asymmetric allyl

Nonsimple relationships between the P*-chiral diamidophosphite and the arylphosphine moieties in Pd-catalyzed asymmetric reactions: Combinatorial approach and P,P*-bidentate phosphine-diamidophosphites

A small family of P,P*-bidentate C1-symmetric ligands containing 1,3,2-diazaphospholidine rings with stereogenic phosphorus atoms has been prepared. Palladium catalytic systems with these phosphine-diamidophosphites afforded 95% and

Diamidophosphites with remote P*-stereocentres and their performance in Pd-catalyzed enantioselective reactions

Diamidophosphite ligands based on 1,1′-bis(hydroxymethyl)ferrocene or N1,N2-bis((S)-1-hydroxy-3,3-dimethylbutan-2-yl)oxalamide and bearing 1,3,2-diazaphospholidine rings with stereogenic phosphorus atoms were obtained. The use of the

Application of pyranoside phosphite-pyridine ligands to enantioselective metal-catalyzed allylic substitutions and conjugate 1,4-additions

A series of glucopyranoside phosphite-pyridine ligands have been applied in the metal-catalyzed allylic substitution and conjugate 1,4-addition reactions of several substrate types. We have been able to identify ligands that provided promising enantioselectivities in the Pd-catalyzed intermolecular allylic substitution of cyclic substrates (ee's up to 86%) and desymmetrization (ee's up to 94%) and in the Cu-catalyzed conjugate addition of challenging aliphatic enones (ee's up to 90%).

Pd-Catalyzed asymmetric transformations involving P*-mono- and P*,N-bidentate diamidophosphites derived from (2S,3S)-N 2,3-dimethyl-N 1-phenylpentane-1,2-diamine

The synthesis of new P*-mono- and P*,N-bidentate diamidophosphites, containing 1,3,2-diazaphospholidine rings formed starting from (2S,3S)-N 2,3-dimethyl-N 1-phenylpentane-1,2-diamine, is described. Comparison of their efficiency in

Phosphites and diamidophosphites based on mono-ethers of BINOL: A comparison of enantioselectivity in asymmetric catalytic reactions

Novel P-monodentate phosphite-type ligands have been synthesized in one step from BINOL mono-tosylate and BINOL mono-(-)-menthylcarbonate. The use of these ligands provides up to 96% ee in Pd-catalyzed asymmetric allylic substitution of (E)-1,3-diphenylal

Naplephos through the looking-glass: Chiral bis(phosphanylamides) based on β-1,2-D-glucodiamine and their application in enantioselective allylic substitutions

The straightforward design of a new library of chiral ligands (elpanphos) based on β-1,2-D-glucodiamine is described, which represents the enantiomeric counterpart of the naplephos library. In this guise, two representative ligands have been successfully

New tagged naplephos ligands for asymmetric allylic substitutions under traditional and unconventional conditions

This paper demonstrates the versatility of the class of chiral ligands naplephos, which has been further refined by preparing new 'tagged' versions for selective use in polar media (e.g., ionic liquids). These modified types, along with the best performin

Chiral (salen)Co(III)(N-benzyl-l-serine)-derived phosphites: monodentate P-ligands for enantioselective catalytic applications

Reaction of the (S,S)-salen-cobalt(III)-N-benzyl-l-serine complex 2 with four diol-derived chlorophosphites afforded phosphites 3a-3d in moderate yields (37-72%). Structural studies of these monodentate phosphite ligands and of their Rh-complexes were per