138624-05-2Relevant articles and documents
A mild radical procedure for the reduction of B-alkylcatecholboranes to alkanes
Pozzi, Davide,Scanlan, Eoin M.,Renaud, Philippe
, p. 14204 - 14205 (2007/10/03)
A mild radical-mediated reduction of organoboranes is reported. The reducing agent is methanol complexed by the Lewis acidic B-methoxycatecholborane. Copyright
Regioselective radical cyclization initiated by the reaction of allylic hydroperoxides with iron(II) sulfate
Masuyama, Araki,Sugawara, Tomohiro,Nojima, Masatomo,McCullough, Kevin J.
, p. 353 - 366 (2007/10/03)
Treatment of 1-methyl-2-methylene-1-cyclohexyl hydroperoxide with a mixture of FeSO4/CuCl2 yielded 1-(1-chlorocyclohexyl)ethanone as the major product consistent with 6-endo-trig cyclization of the intermediate 5-acetylhex-5-enyl rad
Triphenylbismuth dibromide-iodine: An efficient reagent for the dehydration of alcohols
Dorta,Dorta, Rosa L.,Suarez,Suarez, Ernesto,Betancor,Betancor, Carmen
, p. 5035 - 5038 (2007/10/02)
Tertiary and secondary alcohols react under mild conditions with triphenylbismuth dibromide and iodine under an inert atmosphere to give the corresponding most stable alkenes in good yields.
BF3·OEt2 promotes fast, mild, clean and regioselective dehydration of tertiary alcohols
Posner,Shulman-Roskes,Oh,Carry,Green,Clark,Dai,Anjeh
, p. 6489 - 6492 (2007/10/02)
BF3·OEt2 in methylene chloride at 25°C for 2 hours or less is shown to be effective for easy conversion of tertiary alcohols into the corresponding thermodynamically most stable alkenes.