138624-36-9Relevant academic research and scientific papers
Tetracyanoethylene-hydrogen peroxide, a mild epoxidation system of olefins
Masaki,Miura,Mukai,Iwata,Oda,Itoh
, p. 686 - 688 (2007/10/03)
A reagent combination system, tetracyanoethylene-30% hydrogen peroxide, was found to epoxidize olefins efficiently in acetonitrile at room temperature in a stereospecific manner with retention of the configuration of the double bond.
Ethyl Cyanoformate/Hydrogen Peroxide and Related Combination Systems, Novel Epoxidizing Systems of Olefins
Masaki, Yukio,Miura, Tsuyoshi,Mukai, Isao,Itoh, Akichika,Oda, Hirohisa
, p. 1937 - 1940 (2007/10/02)
A combination system of ethyl cyanoformate and hydrogen peroxide was found to epoxidize olefins in a stereospecific manner at room temperature.Asymmetric epoxidation was observed with menthyl cyanoformate/hydrogen peroxide system.
CONJUGATE ADDITION OF ALKYL GROUPS TO α,β-UNSATURATED SULFOXIDES VIA MICHAEL ADDITION OF NITROPARAFFINS AND SUBSEQUENT DENITRATION WITH TRIBUTYLTIN HYDRIDE
Ono, Noboru,Miyake, Hideyoshi,Kamimura, Akio,Tsukui, Nobuo,Kaji, Aritsune
, p. 2957 - 2960 (2007/10/02)
Michael addition of nitroparaffins to α,β-unsaturated sulfoxides is well effected in the presence of DBU.The nitro group in the adduct is replaced by hydrogen with Bu3SnH without influence to the sulfinyl function.The overall reactions provide an efficien
