138638-17-2Relevant articles and documents
CARBOCYCLES FROM CARBOHYDRATES: A FREE RADICAL ROUTE TO AMINOCYCLITOL DERIVATIVES
Marco-Contelles, Jose,Martinez, Luis,Martinez-Grau, Angeles,Pozuelo, Carmen,Jimeno, M. L.
, p. 6437 - 6440 (1991)
Some derivatives of (1R,2R,3R,4S,5R) and (1R,2R,3R,4R,5S)-5-amino-1,2,3,4-cyclohexanetetrol have been synthesized from acyclic carbohydrate intermediates via 6-exo free radical cyclization.
6-Exo Free Radical Cyclization of Acyclic Carbohydrate Intermediates: A New Synthetic Route to Enantiomerically Pure Polyhydroxylated Cyclohexane Derivatives
Marco-Contelles, Jose,Pozuelo, Carmen,Jimeno, M. L.,Martinez, Luis,Martinez-Grau, Angeles
, p. 2625 - 2631 (2007/10/02)
The 6-exo free radical cyclization of conveniently functionalized acyclic carbohydrate derivatives is a new and efficient method for the asymmetric synthesis of polyhydroxylated cyclohexane compounds (aminocyclitols, pseudosugars).The scope and versatilit