138688-70-7

Basic information

• Product Name: (2R,4aR,6S,7R,8R,8aS)-7-Azido-8-benzyloxy-6-nitrooxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine
• Synonyms: (2R,4aR,6S,7R,8R,8aS)-7-Azido-8-benzyloxy-6-nitrooxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine
• CAS NO: 138688-70-7
• Molecular Weight: 428.401
• Mol File: 138688-70-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,4aR,6S,7R,8R,8aS)-7-Azido-8-benzyloxy-6-nitrooxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,4aR,6S,7R,8R,8aS)-7-Azido-8-benzyloxy-6-nitrooxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine(138688-70-7)
• EPA Substance Registry System: (2R,4aR,6S,7R,8R,8aS)-7-Azido-8-benzyloxy-6-nitrooxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine(138688-70-7)

Safety Data

• Hazardous Substances Data: 138688-70-7(Hazardous Substances Data)

Upstream product

• 110522-37-7 1,5-anhydro-3-O-benzyl-4,6-O-benzylidene-2-deoxy-D-arabino-hex-1-enitol 

Downstream Products

• 162678-87-7 Methyl 2-azido-3-O-benzyl-4,6-O-benzylidene-2-deoxy-α-D-glucopyranoside 
• 175978-62-8 (2R,3S,4S,5R,6R)-5-Acetoxy-6-((2R,3S,4R,5R,6S)-2-acetoxymethyl-5-azido-4-benzyloxy-6-methoxy-tetrahydro-pyran-3-yloxy)-4-benzyloxy-3-(4-oxo-pentanoyloxy)-tetrahydro-pyran-2-carboxylic acid methyl ester 
• 175978-56-0 methyl 6-O-acetyl-2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 175978-55-9 methyl 2-azido-3-O-benzyl-2-deoxy-α-D-glucopyranoside 

Relevant articles and documents

L-Iduronic acid derivatives as glycosyl donors

O-[Methyl (2-O-acetyl-3-O-benzyl-4-O-levulinyl-α, and β-L-idopyranosid)uronate]trichloroacetimidate and the corresponding n-pentenyl glycosides are efficient L-iduronic acid glycosyl donors. Both have been used for the high-yielding synthesis of basic disaccharide blocks which are useful for the subsequent synthesis of complex oligosaccharides related to heparin/heparan sulfate, and dermatan sulfate. In contrast, the corresponding thioethyl glycosides, thiophenyl glycosides, and fluoride, did not yield the expected disaccharides.