138688-77-4Relevant academic research and scientific papers
One-Step TEMPO-Catalyzed and Water-Mediated Stereoselective Conversion of Glycals into 2-Azido-2-deoxysugars with a PIFA-Trimethylsilyl Azide Reagent System
Chennaiah, Ande,Vankar, Yashwant D.
supporting information, p. 2611 - 2614 (2018/05/17)
An unprecedented water-mediated and TEMPO-catalyzed, one-step, highly regiospecific and stereoselective functionalization of glycals to 2-azido-2-deoxysugars has been developed using a PIFA-Me3SiN3 reagent system in the presence of B
Synthesis of disaccharidic sub-units of a new series of heparin related oligosaccharides
La Ferla, Barbara,Lay, Luigi,Guerrini, Marco,Poletti, Laura,Panza, Luigi,Russo, Giovanni
, p. 9867 - 9880 (2007/10/03)
The chemical synthesis of disaccharides 1 and 2, useful building-blocks for the preparation of a new series of heparin related oligosaccharides containing the unusual sequence (GlcN-IdoA)(n), is described. In addition, the orthogonality of the protective groups would allow access to a wide array of differently sulfated oligosaccharides. As the simplest members of this new class of oligomer, the synthesis of sulfated disaccharides 3 and 4 fully deprotected is reported.
L-Iduronic acid derivatives as glycosyl donors
Tabeur, Christine,Machetto, Francoise,Mallet, Jean-Maurice,Duchaussoy, Philippe,Petitou, Maurice,Sinay, Pierre
, p. 253 - 276 (2007/10/03)
O-[Methyl (2-O-acetyl-3-O-benzyl-4-O-levulinyl-α, and β-L-idopyranosid)uronate]trichloroacetimidate and the corresponding n-pentenyl glycosides are efficient L-iduronic acid glycosyl donors. Both have been used for the high-yielding synthesis of basic disaccharide blocks which are useful for the subsequent synthesis of complex oligosaccharides related to heparin/heparan sulfate, and dermatan sulfate. In contrast, the corresponding thioethyl glycosides, thiophenyl glycosides, and fluoride, did not yield the expected disaccharides.
