138694-18-5

Upstream product

• 14371-10-9 (E)-3-phenylpropenal 
• 113453-29-5 (2R,3R,4E)-3-Hydroxy-N-methoxy-N,2-dimethyl-5-phenyl-4-pentenamide 
• 74-88-4 methyl iodide 
• 138694-16-3 (4R,5S)-3-<(2R,3R,4E)-3-Hydroxy-2-methyl-5-phenyl-4-pentenoyl>-4-methyl-5-phenyl-2-oxazolidinone 

Downstream Products

• 138694-19-6 (2R,3R,4E)-3-Methoxy-2-methyl-5-phenyl-4-pentenal 
• 130740-44-2 macbecin I 
• 123083-98-7 (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-Amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoic acid 
• 138694-33-4 (2E,4S,5R,6E)-5-Methoxy-2,4-dimethyl-7-phenyl-2,6-heptadien-1-al 
• 138694-31-2 (2E,4S,5R,6E)-5-Methoxy-2,4-dimethyl-7-phenyl-2,6-heptadien-1-ol 
• 138694-22-1 (2R,3R,4E,6S,7R,8E)-N,7-Dimethoxy-3-hydroxy-9-phenyl-N,2,4,6-tetramethyl-4,8-nonadienamide 
• 138694-23-2 (2R,3R,4E,6S,7R,8E)-3-<(tert-Butyldimethylsilyl)oxy>-N,7-dimethoxy-9-phenyl-N,2,4,6-tetramethyl-4,8-nonadienamide 
• 138694-21-0 (4R,5S)-3-<(2R,3R,4E,6S,7R,8E)-3-Hydroxy-7-methoxy-2,4,6-trimethyl-9-phenyl-4,8-nonadienoyl>-4-methyl-5-phenyl-2-oxazolidinone 
• 138694-27-6 (2R,3R,4E,6S,7R,8S,10S,11R)-<(tert-Butyldimethylsilyl)oxy>-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenal 
• 138694-26-5 (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138721-96-7 (2R,3R,4E,6S,7R,8S,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-N,7,8,11-tetramethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138694-29-8 Methyl (2E,4Z,6S,7R,8E,10S,11R,12S,14S,15R)-15-(3-amino-2,5-dimethoxyphenyl)-7-(tert-butyldimethylsiloxy)-11,12,15-trimethoxy-2,6,8,10,14-pentamethyl-2,4,8-pentadecatrienoate 
• 138694-25-4 (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-oxo-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-4-undecenamide 
• 138721-95-6 (2R,3R,4E,6S,7R,10S,11R)-3-(tert-Butyldimethylsilyloxy)-11-(2,5-dimethoxy-3-nitrophenyl)-8-hydroxy-N,7,11-trimethoxy-N,2,4,6,10-pentamethyl-9-<(2-thioxo-3-thiazolidinyl)carbonyl>-4-undecenamide 

Relevant academic research and scientific papers

Enantioselective synthesis of (+)-crocacin C. An example of a highly challenging mismatched double asymmetric δ-stannylcrotylboration reaction

A concise, enantioselective synthesis of (+)-crocacin C is described, featuring a highly diastereoselective mismatched double asymmetric δ-stannylcrotylboration of the stereochemically demanding chiral aldehyde 9 with the bifunctional crotylborane reagent