1387444-10-1

Basic information

• Product Name: 1,5-anhydro 4-O-diphenylphosphino-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol
• Synonyms: 1,5-anhydro 4-O-diphenylphosphino-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol
• CAS NO: 1387444-10-1
• Molecular Weight: 556.641
• Mol File: 1387444-10-1.mol

Chemical Properties

• CAS DataBase Reference: 1,5-anhydro 4-O-diphenylphosphino-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-anhydro 4-O-diphenylphosphino-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol(1387444-10-1)
• EPA Substance Registry System: 1,5-anhydro 4-O-diphenylphosphino-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol(1387444-10-1)

Safety Data

• Hazardous Substances Data: 1387444-10-1(Hazardous Substances Data)

Upstream product

• 4098-06-0 triacetyl-D-galactal 
• 318959-97-6 4,6-di-O-acetyl-1,5-anhydro-2,3-dideoxy-D-threo-hex-2-enitol 
• 226985-33-7 (2R,3R)-2-(hydroxymethyl)-3,6-dihydro-2H-pyran-3-ol 
• 1387444-09-8 1,5-anhydro-2,3-dideoxy-6-O-trityl-D-threo-hex-2-enitol 
• 1079-66-9 chloro-diphenylphosphine 

Relevant articles and documents

Efficient pseudo-enantiomeric carbohydrate olefin ligands

Highly efficient pseudo-enantiomeric olefin ligands were designed from d-glucose and d-galactose. These ligands yield consistently excellent levels of enantioselectivity in Rh(I)-catalyzed 1,4-additions of aryl- and alkenylboronic acids to achiral enones and high diastereoselectivity with chiral substrates. Contrary to established olefin ligands, they are obtained enantiomerically pure via short syntheses without racemic resolution steps, making them a valuable addition to the arsenal of chiral ligands with olefinic donor sites.