138751-61-8

Upstream product

• 133732-91-9 tert-butyldimethylsilyl triflate 
• 77877-20-4 (4R,5S)-4-methyl-5-phenyl-3-propionyloxazolidin-2-one 
• 98-01-1 furfural 
• 95481-54-2 <4R-<4α(2R^*,3R^*),5α>>-3-<3-(2-furanyl)-3-hydroxy-2-methyl-1-oxopropyl>-4-methyl-5-phenyl-2-oxazolidinone 
• 69739-34-0 t-butyldimethylsiyl triflate 

Downstream Products

• 138666-93-0 <4R,5S>-4'-methyl-5'-phenyl-2'-oxazolidinon-3'-yl-(O-tert-butyldimethylsilyl-6-methyl-2,3,6-trideoxy-β-L-threo-hept-2-en-4-ulo-pyranosiduron)imide 
• 175356-50-0 (4R,5S)-3-{(E)-(2R,3S,6S)-6-[(2R,3S,5S,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-5-methyl-tetrahydro-pyran-2-yl]-3-hydroxy-2-methoxy-4-methyl-hept-4-enoyl}-4-methyl-5-phenyl-oxazolidin-2-one 
• 175356-48-6 (4R,5S)-3-{(E)-(2R,3R,6S)-6-[(2R,3S,5S,6R)-6-(tert-Butyl-dimethyl-silanyloxy)-3-methoxy-5-methyl-tetrahydro-pyran-2-yl]-3-hydroxy-2,4-dimethyl-hept-4-enoyl}-4-methyl-5-phenyl-oxazolidin-2-one 
• 175356-53-3 <2α(2Z,4S,5R,6E,8S),3β,5α,6α>-4,6-dimethyl-1-tert-butyldiphenylsilyloxy-3-triisopropylsiloxy-8--2,6-octadiene 
• 138666-94-1 <4R,5S>-4'-methyl-5'-phenyl-2'-oxazolidinon-3'-yl-(O-tert-butyldimethylsilyl-2,6-dimethyl-2,3,6-trideoxy-β-L-xylo-hept-4-ulo-pyranosiduron)imide 
• 136113-81-0 O-tert-butyldimethylsilyl-2,6-dimethyl-7-O-(tert-butyldimethylsilyl)-4-O-(4-nitrobenzoate)-2,3,6-trideoxy-β-L-galacto-heptopyranoside 

Relevant academic research and scientific papers

Novel approach to the ansamycin antibiotics macbecin I and herbimycin A. A formal total synthesis of (+)-macbecin I

The asymmetric syntheses of 25 and 29, which constitutes the C(3)-C(15) segment of the stereochemically complex ansa chain of (+)-macbecin I (1) and herbimycin A (2), respectively, have been achieved. The approach features the furan-hydropyranone transfor